Figures (8)  Tables (1)
    • Figure 1. 

      Contents of Na or K elements in reconstituted tobacco sheets after adding alkali metal salts (measured by ICP‒OES).

    • Figure 2. 

      TG and DTG curves of reconstituted tobacco sheets with varying additions of (a) Na salt and (b) K salt.

    • Figure 3. 

      (a) Weight loss transition temperatures of reconstituted tobacco sheets during pyrolysis at 35–500 °C. (b) Weight loss of reconstituted tobacco sheets in weight loss Stages I–III. Weight loss (left) at 100–300 °C and maximum weight loss rate at temperatures below 500 °C (right) of reconstituted tobacco sheets with added (c) Na salt or (d) K salt.

    • Figure 4. 

      Contents of (a) acetic acid and monoacetin, (b) glycerin and nicotine, (c) 1-hydroxy-2-propanone and 2-furan methanol, and (d) phenol and megastigmatrienone in the pyrolysis gas of reconstituted tobacco sheets with different amounts of added Na salt at 300 °C (semiquantitative results represented by the peak area measured via Py-GC/MS).

    • Figure 5. 

      Contents of (a) acetic acid and monoacetin, (b) glycerin and nicotine, (c) 1-hydroxy-2-propanone and 2-furan methanol, and (d) phenol and megastigmatrienone in the pyrolysis gas of reconstituted tobacco sheets with different amounts of added K salt at 300 °C (semiquantitative restults represented by the peak area measured via Py-GC/MS).

    • Figure 6. 

      TG and DTG curves of (a) the KB sample, (b) the N5 sample, and (c) the K5 sample under different heating rates (5, 10, 15, and 20 °C/min, respectively).

    • Figure 7. 

      Linear relationships between lgβ and 1/T × 103 at different conversion ratios (α) for (a) the KB sample, (b) the N5 sample, and (c) the K5 sample. (d) Linear relationships between ln(β/TP2) and 1/TP × 103 for the KB sample, the N5 sample, and the K5 sample.

    • Figure 8. 

      Eα for the pyrolysis of reconstituted tobacco sheets (KB, K5, N5) at different conversion ratios (α).

    • α KB N5 K5
      Eα/(kJ·mol−1) R2 Eα/(kJ·mol−1) R2 Eα/(kJ·mol−1) R2
      0.1 94.17 0.96 96.21 0.93 94.08 0.99
      0.2 91.21 0.92 89.41 0.93 95.08 0.99
      0.3 183.64 0.99 98.74 0.99 126.00 0.99
      0.4 196.93 0.99 116.92 0.99 143.59 0.99
      0.5 194.36 0.99 122.95 0.99 153.25 0.99
      0.6 203.14 0.99 127.86 0.99 161.73 0.99
      0.7 224.98 0.99 131.85 0.99 172.86 0.99
      0.8 238.99 0.99 110.38 0.97 239.92 0.99

      Table 1. 

      Kinetic parameters and squared correlation coefficients of the FWO method for the pyrolysis of the blank sample and the Na salt-doped and K salt-doped samples.