| [1] |
Feng J, Liu L, Zhang Y, Wang Q, Liang H, et al. 2023. Rethinking the pathway to sustainable fire retardants. |
| [2] |
McKenna ST, Jones N, Peck G, Dickens K, Pawelec W, et al. 2019. Fire behaviour of modern façade materials–Understanding the Grenfell Tower fire. |
| [3] |
Fu T, Guo DM, Chen L, Wu WS, Wang XL, et al. 2020. Fire hazards management for polymeric materials via synergy effects of pyrolysates-fixation and aromatized-charring. |
| [4] |
Irvine D, McCluskey J, Robinson I. 2000. Fire hazards and some common polymers. |
| [5] |
Costes L, Laoutid F, Brohez S, Dubois P. 2017. Bio-based flame retardants: When nature meets fire protection. |
| [6] |
Quan Y, Zhang Z, Tanchak RN, Wang Q. 2022. A review on cone calorimeter for assessment of flame-retarded polymer composites. |
| [7] |
Wang X, Kalali EN, Wan JT, Wang DY. 2017. Carbon-family materials for flame retardant polymeric materials. |
| [8] |
Shen R, Quan Y, Zhang Z, Ma R, Wang Q. 2022. Metal-organic framework as an efficient synergist for intumescent flame retardants against highly flammable polypropylene. |
| [9] |
Quan Y, Shen R, Schweizer C, Parajuli P, Zhang Z, et al. 2023. Synergistic effects of zeolitic imidazolate frameworks (ZIFs) with different transition metals on intumescent flame-retarded polypropylene composites: a comparative study. |
| [10] |
Cheng XW, Zhang W, Wu YX, Ma YD, Xu JT, et al. 2021. Borate functionalized caramel as effective intumescent flame retardant for wool fabric. |
| [11] |
Shen R, Yan TH, Ma R, Joseph E, Quan Y, et al. 2021. Flammability and thermal kinetic analysis of UiO-66-based PMMA polymer composites. |
| [12] |
Dasari A, Yu ZZ, Cai GP, Mai YW. 2013. Recent developments in the fire retardancy of polymeric materials. |
| [13] |
Morgan AB. 2019. The future of flame retardant polymers–unmet needs and likely new approaches. |
| [14] |
Pachauri RK, Reisinger A. 2007. Climate change 2007: Synthesis report. Contribution of working groups I, II and III to the fourth assessment report of the Intergovernmental Panel on Climate Change. IPCC |
| [15] |
Réti C, Casetta M, Duquesne S, Bourbigot S, Delobel R. 2008. Flammability properties of intumescent PLA including starch and lignin. |
| [16] |
Xing W, Yuan H, Zhang P, Yang H, Song L, et al. 2013. Functionalized lignin for halogen-free flame retardant rigid polyurethane foam: Preparation, thermal stability, fire performance and mechanical properties. |
| [17] |
Liu Y, Zhang A, Cheng Y, Li M, Cui Y, et al. 2023. Recent advances in biomass phytic acid flame retardants. |
| [18] |
Alongi J, Di Blasio A, Milnes J, Malucelli G, Bourbigot S, et al. 2015. Thermal degradation of DNA, an all-in-one natural intumescent flame retardant. |
| [19] |
Costes L, Laoutid F, Dumazert L, Lopez-Cuesta JM, Brohez S, et al. 2015. Metallic phytates as efficient bio-based phosphorous flame retardant additives for poly (lactic acid). |
| [20] |
Yang H, Yu B, Xu X, Bourbigot S, Wang H, et al. 2020. Lignin-derived bio-based flame retardants toward high-performance sustainable polymeric materials. |
| [21] |
De Chirico A, Armanini M, Chini P, Cioccolo G, Provasoli F, et al. 2003. Flame retardants for polypropylene based on lignin. |
| [22] |
He W, Song P, Yu B, Fang Z, Wang H. 2020. Flame retardant polymeric nanocomposites through the combination of nanomaterials and conventional flame retardants. |
| [23] |
Zhang R, Xiao X, Tai Q, Huang H, Hu Y. 2012. Modification of lignin and its application as char agent in intumescent flame-retardant poly (lactic acid). |
| [24] |
Illy N, Fache M, Ménard R, Negrell C, Caillol S, et al. 2015. Phosphorylation of bio-based compounds: the state of the art. |
| [25] |
Velencoso MM, Battig A, Markwart JC, Schartel B, Wurm FR. 2018. Molecular firefighting—how modern phosphorus chemistry can help solve the challenge of flame retardancy. |
| [26] |
Zhao X, Guerrero FR, Llorca J, Wang DY. 2016. New superefficiently flame-retardant bioplastic poly (lactic acid): flammability, thermal decomposition behavior, and tensile properties. |
| [27] |
Tao K, Li J, Xu L, Zhao X, Xue L, et al. 2011. A novel phosphazene cyclomatrix network polymer: Design, synthesis and application in flame retardant polylactide. |
| [28] |
Bauer KN, Tee HT, Velencoso MM, Wurm FR. 2017. Main-chain poly(phosphoester)s: history, syntheses, degradation, bio-and flame-retardant applications. |
| [29] |
Fang Y, Liu X, Tao X. 2019. Intumescent flame retardant and anti-dripping of PET fabrics through layer-by-layer assembly of chitosan and ammonium polyphosphate. |
| [30] |
Chen M-J, Lazar S, Kolibaba TJ, Shen R, Quan Y, et al. 2020. Environmentally benign and self-extinguishing multilayer nanocoating for protection of flammable foam. |
| [31] |
Thakur VK, Thakur MK, Raghavan P, Kessler MR. 2014. Progress in green polymer composites from lignin for multifunctional applications: a review. |
| [32] |
Azman Mohammad Taib MN, Hamidon TS, Garba ZN, Trache D, Uyama H, et al. 2022. Recent progress in cellulose-based composites towards flame retardancy applications. |
| [33] |
Wang M, Yin GZ, Yang Y, Fu W, Díaz Palencia JL, et al. 2023. Bio-based flame retardants to polymers: a review. |
| [34] |
Zhang J, Li Z, Zhang L, García Molleja J, Wang DY. 2019. Bimetallic metal-organic frameworks and graphene oxide nano-hybrids for enhanced fire retardant epoxy composites: a novel carbonization mechanism. |
| [35] |
Fang F, Ran S, Fang Z, Song P, Wang H. 2019. Improved flame resistance and thermo-mechanical properties of epoxy resin nanocomposites from functionalized graphene oxide via self-assembly in water. |
| [36] |
Lazar S, Shen R, Quan Y, Palen B, Wang Q, et al. 2021. Mixed solvent synthesis of polydopamine nanospheres for sustainable multilayer flame retardant nanocoating. |
| [37] |
Palen B, Kolibaba TJ, Brehm JT, Shen R, Quan Y, et al. 2021. Clay-filled polyelectrolyte complex nanocoating for flame-retardant polyurethane foam. |
| [38] |
Ma R, Shen R, Quan Y, Wang Q. 2022. Tunable flammability studies of graphene quantum dots-based polystyrene nanocomposites using microscale combustion calorimeter. |
| [39] |
Smith DL, Rodriguez-Melendez D, Cotton SM, Quan Y, Wang Q, et al. 2022. Non-isocyanate polyurethane bio-foam with inherent heat and fire resistance. |
| [40] |
Zhao M, Chen H, Zhu Z, Zhu X, Quan Y, et al. 2022. Multifunctional polyethylene nanocomposites based on polyethylene-grafted α-zirconium phosphate nanoplatelets. |
| [41] |
Li WX, Zhang HJ, Hu XP, Yang WX, Cheng Z, et al. 2020. Highly efficient replacement of traditional intumescent flame retardants in polypropylene by manganese ions doped melamine phytate nanosheets. |
| [42] |
Ma R, Shen R, Quan Y, Wang Q. 2023. Preparation of graphene quantum dots decorated montmorillonite to reinforce fire retardancy of polystyrene. |
| [43] |
Quan Y, Shen R, Ma R, Zhang Z, Wang Q. 2022. Sustainable and efficient manufacturing of metal-organic framework-based polymer nanocomposites by reactive extrusion. |
| [44] |
Wang S, Zhang P, Li Y, Li J, Li X, et al. 2023. Recent advances and future challenges of the starch-based bio-composites for engineering applications. |
| [45] |
Aggarwal P, Dollimore D. 1998. A thermal analysis investigation of partially hydrolyzed starch. |
| [46] |
Xu Y, Miladinov V, Hanna MA. 2004. Synthesis and characterization of starch acetates with high substitution. |
| [47] |
Battegazzore D, Alongi J, Fontaine G, Frache A, Bourbigot S, et al. 2015. Bulk vs. surface flame retardancy of fully bio-based polyamide 10, 10. |
| [48] |
Nie S, Song L, Guo Y, Wu K, Xing W, et al. 2009. Intumescent flame retardation of starch containing polypropylene semibiocomposites: flame retardancy and thermal degradation. |
| [49] |
Gavgani JN, Adelnia H, Mir Mohamad Sadeghi G, Zafari F. 2014. Intumescent flame retardant polyurethane/starch composites: thermal, mechanical, and rheological properties. |
| [50] |
Kumar S, Shukla SK. 2023. Synergistic evolution of flame-retardant hybrid structure of poly vinyl alcohol, starch and kaolin for coating on wooden substrate. |
| [51] |
Ji W, Wang D, Guo J, Fei B, Gu X, et al. 2020. The preparation of starch derivatives reacted with urea-phosphoric acid and effects on fire performance of expandable polystyrene foams. |
| [52] |
Zhou H, Lu Y, Liang M, Jin Q, Yang Y, et al. 2024. A cationic, durable, P/N-containing starch-based flame retardant for cotton fabrics. |
| [53] |
Zheng L, Zhan J, Wang J, Xu Z, Mu X. 2024. Highly efficient flame retardancy and fire spread behavior of rigid polyurethane foams with extremely low content of flame retardant. |
| [54] |
Mu X, Jin Z, Chu F, Cai W, Zhu Y, et al. 2022. High-performance flame-retardant polycarbonate composites: Mechanisms investigation and fire-safety evaluation systems establishment. |
| [55] |
Chen Q, Liu Z, Xie G, Zhao W, Chen G, et al. 2023. A novel starch-based synergistic flame retardant for the treatment of insulating paper. |
| [56] |
Chen S, Li H, Lai X, Zhang S, Zeng X. 2021. Superhydrophobic and phosphorus-nitrogen flame-retardant cotton fabric. |
| [57] |
Shen S, Du J, Guo X, Wen Y, Yang HF. 2015. Adsorption behavior of pH-dependent phytic acid micelles at the copper surface observed by Raman and electrochemistry. |
| [58] |
Feizollahi E, Mirmahdi RS, Zoghi A, Zijlstra RT, Roopesh M, et al. 2021. Review of the beneficial and anti-nutritional qualities of phytic acid, and procedures for removing it from food products. |
| [59] |
Liu X, Zhang Q, Cheng B, Ren Y, Zhang Y, et al. 2018. Durable flame retardant cellulosic fibers modified with novel, facile and efficient phytic acid-based finishing agent. |
| [60] |
Sai T, Ran S, Guo Z, Yan H, Zhang Y, et al. 2021. Transparent, highly thermostable and flame retardant polycarbonate enabled by rod-like phosphorous-containing metal complex aggregates. |
| [61] |
Zhang B, Feng Z, Han X, Wang B, Yang S, et al. 2021. Effect of ammonium polyphosphate/cobalt phytate system on flame retardancy and smoke & toxicity suppression of rigid polyurethane foam composites. |
| [62] |
Gong W, Fan M, Luo J, Liang J, Meng X. 2021. Effect of nickel phytate on flame retardancy of intumescent flame retardant polylactic acid. |
| [63] |
Cheng L, Wu W, Meng W, Xu S, Han H, et al. 2018. Application of metallic phytates to poly (vinyl chloride) as efficient biobased phosphorous flame retardants. |
| [64] |
Liu W, Shi R, Zhang Z, Yan M, Chen X, et al. 2021. Coordination driven layer-by-layer deposition technology used for fabrication of flame retardant polyamide 66 fabric. |
| [65] |
Pan Y, Liu L, Zhao H. 2018. Recyclable flame retardant paper made from layer-by-layer assembly of zinc coordinated multi-layered coatings. |
| [66] |
Khanal S, Lu Y, Dang L, Ali M, Xu S. 2020. Effects of α-zirconium phosphate and zirconium organophosphonate on the thermal, mechanical and flame retardant properties of intumescent flame retardant high density polyethylene composites. |
| [67] |
Xu Y, Li J, Shen R, Wang Z, Hu P, et al. 2021. Experimental study on the synergistic flame retardant effect of bio-based magnesium phytate and rice husk ash on epoxy resins. |
| [68] |
Wang L, Wei Y, Deng H, Lyu R, Zhu J, et al. 2021. Synergistic flame retardant effect of barium phytate and intumescent flame retardant for epoxy resin. |
| [69] |
Ma D, Zhao P, Li J. 2017. Effects of zinc phytate on flame retardancy and thermal degradation behaviors of intumescent flame-retardant polypropylene. |
| [70] |
Huang G, Pan YT, Liu L, Song P, Yang R. 2025. Metal-organic frameworks and their derivatives for sustainable flame-retardant polymeric materials. |
| [71] |
Yuan J, Pan YT, Lin Y, Zhang W, Du R, et al. 2025. Introduction of phosphorous to metal-organic frameworks for fire-safe polymers: from synthesis to application. |
| [72] |
Rosely CS, Joseph AM, Leuteritz A, Gowd EB. 2020. Phytic acid modified boron nitride nanosheets as sustainable multifunctional nanofillers for enhanced properties of poly (l-lactide). ACS Sustainable Chemistry & Engineering 8(4):1868−78 |
| [73] |
Li Z, Yu S, Gong Z, Yao X, Zhang J, et al. 2025. A natural glue paste aminated graphene oxide onto ammonium polyphosphate towards "multiphase integrated" polymer composites: synthesis and application. |
| [74] |
Sun X, Miao W, Pan YT, Song P, Gaan S, et al. 2025. Metal-organic frameworks: a solution for greener polymeric materials with low fire hazards. |
| [75] |
Ye G, Huo S, Wang C, Shi Q, Liu Z, Wang H. 2021. One-step and green synthesis of a bio-based high-efficiency flame retardant for poly (lactic acid). |
| [76] |
Huang Z, Wang Z. 2021. Synthesis of a bio‐based piperazine phytate flame retardant for epoxy resin with improved flame retardancy and smoke suppression. |
| [77] |
Feng Y, Zhou Y, Li D, He S, Zhang F, et al. 2017. A plant-based reactive ammonium phytate for use as a flame-retardant for cotton fabric. |
| [78] |
Cheng XW, Tang RC, Yao F, Yang XH. 2019. Flame retardant coating of wool fabric with phytic acid/polyethyleneimine polyelectrolyte complex. |
| [79] |
Yang W, Zhang H, Hu X, Liu Y, Zhang S, et al. 2021. Self-assembled bio-derived microporous nanosheet from phytic acid as efficient intumescent flame retardant for polylactide. |
| [80] |
Yang YX, Haurie L, Zhang J, Zhang XQ, Wang RH, et al. 2020. Effect of bio-based phytate (PA-THAM) on the flame retardant and mechanical properties of polylactide (PLA). |
| [81] |
Yang Y, Wang X, Fei B, Li H, Gu X, et al. 2021. Preparation of phytic acid‐based green intumescent flame retardant and its application in PLA nonwovens. |
| [82] |
Fang F, Huo S, Shen H, Ran S, Wang H, et al. 2020. A bio-based ionic complex with different oxidation states of phosphorus for reducing flammability and smoke release of epoxy resins. |
| [83] |
Li P, Wang B, Xu YJ, Jiang Z, Dong C, et al. 2019. Ecofriendly flame-retardant cotton fabrics: preparation, flame retardancy, thermal degradation properties, and mechanism. |
| [84] |
Zhang J, Li Z, Zhang L, Yang Y, Wang DY. 2019. Green synthesis of biomass phytic acid-functionalized UiO-66-NH2 hierarchical hybrids toward fire safety of epoxy resin. |
| [85] |
Yang P, Wu H, Yang F, Yang J, Wang R, et al. 2021. A novel self-assembled graphene-based flame retardant: synthesis and flame retardant performance in PLA. |
| [86] |
Hu Y, Ye Y, Wang J, Zhang T, Jiang S, et al. 2025. Functionalization of chitosan and its application in flame retardants: a review. |
| [87] |
Shi X, Jiang S, Hu Y, Peng X, Yang H, et al. 2018. Phosphorylated chitosan-cobalt complex: a novel green flame retardant for polylactic acid. |
| [88] |
Zhang M, Cheng Y, Li Z, Li X, Yu L, et al. 2019. Biomass chitosan-induced Fe3O4 functionalized halloysite nanotube composites: preparation, characterization and flame-retardant performance. |
| [89] |
Hatami M, Sharifi A, Karimi-Maleh H, Agheli H, Karaman C. 2022. Simultaneous improvements in antibacterial and flame retardant properties of PET by use of bio-nanotechnology for fabrication of high performance PET bionanocomposites. |
| [90] |
Carosio F, Ghanadpour M, Alongi J, Wågberg L. 2018. Layer-by-layer-assembled chitosan/phosphorylated cellulose nanofibrils as a bio-based and flame protecting nano-exoskeleton on PU foams. |
| [91] |
Lin B, Yuen ACY, Li A, Zhang Y, Chen TBY, et al. 2020. MXene/chitosan nanocoating for flexible polyurethane foam towards remarkable fire hazards reductions. |
| [92] |
Lv Z, Hu YT, Guan JP, Tang RC, Chen GQ. 2019. Preparation of a flame retardant, antibacterial, and colored silk fabric with chitosan and vitamin B2 sodium phosphate by electrostatic layer by layer assembly. |
| [93] |
Sirviö JA, Kantola AM, Komulainen S, Filonenko S. 2021. Aqueous modification of chitosan with itaconic acid to produce strong oxygen barrier film. |
| [94] |
Mahaninia MH, Wang Z, Rajabi-Abhari A, Yan N. 2023. Self-healing, flame-retardant, and antimicrobial chitosan-based dynamic covalent hydrogels. |
| [95] |
Khademibami L, Barnes HM, Jeremic D, Shmulsky R, Bourne K, et al. 2020. Antifungal activity and fire resistantance properties of nano-chitosan treated wood. Bioresources 15 (3): 5926-39 |
| [96] |
Solimando X, Kennedy E, David G, Champagne P, Cunningham MF. 2020. Phosphorus-containing polymers synthesised via nitroxide-mediated polymerisation and their grafting on chitosan by grafting to and grafting from approaches. |
| [97] |
Zhou Y, Tawiah B, Noor N, Zhang Z, Sun J, et al. 2021. A facile and sustainable approach for simultaneously flame retarded, UV protective and reinforced poly (lactic acid) composites using fully bio-based complexing couples. |
| [98] |
Liu X, Sun J, Zhang S, Guo J, Tang W, et al. 2019. Effects of carboxymethyl chitosan microencapsulated melamine polyphosphate on the flame retardancy and water resistance of thermoplastic polyurethane. |
| [99] |
Cheng C, Yan J, Lu Y, Ma W, Li C, et al. 2021. Effect of chitosan/lignosulfonate microencapsulated red phosphorus on fire performance of epoxy resin. |
| [100] |
Lou G, Ma Z, Dai J, Bai Z, Fu S, et al. 2021. Fully biobased surface-functionalized microcrystalline cellulose via green self-assembly toward fire-retardant, strong, and tough epoxy biocomposites. |