[1]

Nazarian-Samani M, Myung ST. 2024. Navigating the progress and challenges of solid-state metal–oxygen batteries for the sustainable energy horizon: a comprehensive review and future prospects. Progress in Materials Science 146:101337

doi: 10.1016/j.pmatsci.2024.101337
[2]

Patel M, Mishra K, Banerjee R, Chaudhari J, Kanchan DK, et al. 2023. Fundamentals, recent developments and prospects of lithium and non-lithium electrochemical rechargeable battery systems. Journal of Energy Chemistry 81:221−259

doi: 10.1016/j.jechem.2023.02.023
[3]

Du D, Zhu Z, Chan KY, Li F, Chen J. 2022. Photoelectrochemistry of oxygen in rechargeable Li–O2 batteries. Chemical Society Reviews 51:1846−1860

doi: 10.1039/d1cs00877c
[4]

Bruce PG, Freunberger SA, Hardwick LJ, Tarascon JM. 2012. Li–O2 and Li–S batteries with high energy storage. Nature Materials 11:19−29

doi: 10.1038/nmat3191
[5]

Wu Z, Tian Y, Chen H, Wang L, Qian S, et al. 2022. Evolving aprotic Li–air batteries. Chemical Society Reviews 51:8045−8101

doi: 10.1039/d2cs00003b
[6]

Sandhiya S, Elumalai P. 2025. Stability challenges in non-aqueous Li-O2 batteries and their protective strategies: a comprehensive review on electrode and electrolyte engineering. Journal of Materials Chemistry A 14(5):2565−2612

doi: 10.1039/d5ta06153a
[7]

Hossain MI, Tareq FK, Rudra S. 2025. Light-driven photocathodes in Li/Zn-O2 (air) batteries: an analytical review, technological breakthroughs and future challenges. Energy Storage Materials 75:104025

doi: 10.1016/j.ensm.2025.104025
[8]

Zhou Y, Hong G, Zhang W. 2024. Nanoengineering of cathode catalysts for Li–O2 batteries. ACS Nano 18:16489−16504

doi: 10.1021/acsnano.4c04420
[9]

Chen H, Cao J, Zhao D, Niu F. 2025. Photocathode materials for Li–O2 batteries: progresses and perspectives. Advanced Energy Materials 15(21):2500250

doi: 10.1002/aenm.202500250
[10]

Zhang Z, Xiao X, Zhu X, Tan P. 2023. Addressing transport issues in non-aqueous Li–air batteries to achieving high electrochemical performance. Electrochemical Energy Reviews 6(1):18

doi: 10.1007/s41918-022-00157-3
[11]

Liu J, Li Y, Ding Y, Wu L, Qin J, et al. 2025. A bifunctional imidazolyl iodide mediator of electrolyte boosts cathode kinetics and anode stability towards low overpotential and long-life Li-O2 batteries. Angewandte Chemie International Edition 64(10):e202421107

doi: 10.1002/anie.202421107
[12]

Guo Y, Wang P, Liu Y, Guo S, Shi L, et al. 2024. Dual-type atomic Ru promoted bifunctional catalytic process realizing ultralow overpotential for Li-O2 batteries. Applied Catalysis B: Environment and Energy 356:124203

doi: 10.1016/j.apcatb.2024.124203
[13]

Tian J, Rao Y, Shi W, Yang J, Ning W, et al. 2023. Sabatier relations in electrocatalysts based on high-entropy alloys with wide-distributed d-band centers for Li-O2 batteries. Angewandte Chemie International Edition 62(44):e202310894

doi: 10.1002/anie.202310894
[14]

Sun B, Zheng W, Kang C, Xie B, Qian Z, et al. 2023. Tailoring the p-band center of N-S pair for accelerating high-performance lithium–oxygen battery. Small 19(22):2207461

doi: 10.1002/smll.202207461
[15]

Liang Z, Lu YC. 2016. Critical role of redox mediator in suppressing charging instabilities of lithium–oxygen batteries. Journal of the American Chemical Society 138:7574−7583

doi: 10.1021/jacs.6b01821
[16]

Tan C, Cao D, Zheng L, Shen Y, Chen L, et al. 2022. True reaction sites on discharge in Li–O2 batteries. Journal of the American Chemical Society 144:807−815

doi: 10.1021/jacs.1c09916
[17]

Wang Y, Lai NC, Lu YR, Zhou Y, Dong CL, et al. 2018. A solvent-controlled oxidation mechanism of Li2O2 in lithium-oxygen batteries. Joule 2:2364−2380

doi: 10.1016/j.joule.2018.07.021
[18]

Tan P, Jiang HR, Zhu XB, An L, Jung CY, et al. 2017. Advances and challenges in lithium-air batteries. Applied Energy 204:780−806

doi: 10.1016/j.apenergy.2017.07.054
[19]

Yan H, Wang WW, Wu TR, Gu Y, Li KX, et al. 2023. Morphology-dictated mechanism of efficient reaction sites for Li2O2 decomposition. Journal of the American Chemical Society 145:11959−11968

doi: 10.1021/jacs.2c12267
[20]

Wang Y, Lu YC. 2019. Isotopic labeling reveals active reaction interfaces for electrochemical oxidation of lithium peroxide. Angewandte Chemie International Edition 58:6962−6966

doi: 10.1002/anie.201901350
[21]

Yang Y, Zhang T, Wang X, Chen L, Wu N, et al. 2016. Tuning the morphology and crystal structure of Li2O2: a graphene model electrode study for Li–O2 battery. ACS Applied Materials & Interfaces 8:21350−21357

doi: 10.1021/acsami.6b05660
[22]

Yang Y, Liu W, Wu N, Wang X, Zhang T, et al. 2017. Tuning the morphology of Li2O2 by noble and 3d metals: a planar model electrode study for Li–O2 battery. ACS Applied Materials & Interfaces 9:19800−19806

doi: 10.1021/acsami.7b02663
[23]

Zhang T, Sun H, Zhang X, Wang X, Li J, et al. 2024. Effect of electrolyte level on performance and mass transfer of non-aqueous lithium-oxygen battery. Journal of Power Sources 623:235425

doi: 10.1016/j.jpowsour.2024.235425
[24]

Zhou Y, Zhao Y, Liu Z, Peng Z, Wang L, et al. 2021. Confining Li2O2 in tortuous pores of mesoporous cathodes to facilitate low charge overpotentials for Li-O2 batteries. Journal of Energy Chemistry 55:55−61

doi: 10.1016/j.jechem.2020.06.063
[25]

Zhang W, Tang S, Chen Z, Xiong X, Chen B, et al. 2022. The controllable construction of nanochannel in two-dimensional lamellar film for efficient oxygen reduction reaction and lithium-oxygen batteries. Chemical Engineering Journal 430:132489

doi: 10.1016/j.cej.2021.132489
[26]

Hayat K, Bahamon D, Vega LF, AlHajaj A. 2025. Multiscale design of tailored cathode materials for extended-capacity Li-O2 batteries. Journal of Energy Storage 117:116206

doi: 10.1016/j.est.2025.116206
[27]

Wang Y, Zang L, Dou S, Hao L. 2025. A Li-O2 battery model coupled with LiO2 and Li2O2 reveals regulation mechanism of deposited product composition on mass transport and electron transfer. Applied Energy 391:125934

doi: 10.1016/j.apenergy.2025.125934
[28]

Li D, Long X, Wu Y, Hou H, Wang X, et al. 2022. Hierarchically porous and defective carbon fiber cathode for efficient Zn-air batteries and microbial fuel cells. Advanced Fiber Materials 4:795−806

doi: 10.1007/s42765-022-00139-6
[29]

Wei J, Hu Y, Liang Y, Kong B, Zhang J, et al. 2015. Nitrogen-doped nanoporous carbon/graphene nano-sandwiches: synthesis and application for efficient oxygen reduction. Advanced Functional Materials 25:5768−5777

doi: 10.1002/adfm.201502311
[30]

Cao Y, Lu H, Xu B, Yang W, Hong Q. 2019. Nitrogen/sulfur dual-doped porous carbon nanofibers with Co9S8 nanoparticles encapsulated by graphitic shells: a highly active stable free-standing air electrode for rechargeable non-aqueous Li-O2 batteries and primary alkaline Al-air batteries. Chemical Engineering Journal 378:122247

doi: 10.1016/j.cej.2019.122247
[31]

Zhao T, Yao Y, Yuan Y, Wang M, Wu F, et al. 2021. A universal method to fabricating porous carbon for Li-O2 battery. Nano Energy 82:105782

doi: 10.1016/j.nanoen.2021.105782
[32]

Lee M, Yoo Y, Kwak JH, Yun YS, Jung HG, et al. 2021. Effect of surface characteristics of carbon host on electrochemical performance of nonaqueous Li–O2 batteries. Chemical Engineering Journal 412:128549

doi: 10.1016/j.cej.2021.128549
[33]

Tian M, Wei C, Sun Z, Yang R, Strasser P. 2021. Unraveling the lithiophilic nature of heteroatom-doped carbons for efficient oxygen reduction in Li–O2 batteries. Carbon 178:436−442

doi: 10.1016/j.carbon.2021.03.002
[34]

Aswathappa S, Dai LD, Dhas SSJ, Matheswaran P, Kumar RS, et al. 2024. Acoustic shock wave processing on amorphous carbon quantum dots - correlation between spectroscopic-morphological-magnetic and electrical conductivity properties. Ceramics International 50:17011−17019

doi: 10.1016/j.ceramint.2024.02.178
[35]

Chokradjaroen C, Watanabe H, Ishii T, Ishizaki T. 2021. Simultaneous synthesis of graphite-like and amorphous carbon materials via solution plasma and their evaluation as additive materials for cathode in Li-O2 battery. Scientific Reports 11:6261

doi: 10.1038/s41598-021-85392-2
[36]

Yuan R, Guo Y, Gurgan I, Siddique N, Li YS, et al. 2025. Raman spectroscopy analysis of disordered and amorphous carbon materials: a review of empirical correlations. Carbon 238:120214

doi: 10.1016/j.carbon.2025.120214
[37]

Ferrari AC, Robertson J. 2000. Interpretation of Raman spectra of disordered and amorphous carbon. Physical Review B 61:14095−14107

doi: 10.1103/PhysRevB.61.14095
[38]

Zhang X, Zhang X, Zhao S, Wang YQ, Lin X, et al. 2021. Precursor modulated active sites of nitrogen doped graphene-based carbon catalysts via one-step pyrolysis method for the enhanced oxygen reduction reaction. Electrochimica Acta 370:137712

doi: 10.1016/j.electacta.2021.137712
[39]

Cheng G, Zhang W, Wang W, Wang H, Wang Y, et al. 2022. Sulfur and nitrogen codoped cyanoethyl cellulose‐derived carbon with superior gravimetric and volumetric capacity for potassium ion storage. Carbon Energy 4:986−1001

doi: 10.1002/cey2.233
[40]

Gao Y, Xiao Z, Kong D, Iqbal R, Yang QH, et al. 2019. N, P co-doped hollow carbon nanofiber membranes with superior mass transfer property for trifunctional metal-free electrocatalysis. Nano Energy 64:103879

doi: 10.1016/j.nanoen.2019.103879
[41]

Zhang X, Wen X, Pan C, Xiang X, Hao C, et al. 2022. N species tuning strategy in N, S co-doped graphene nanosheets for electrocatalytic activity and selectivity of oxygen redox reactions. Chemical Engineering Journal 431:133216

doi: 10.1016/j.cej.2021.133216
[42]

Zhang J, Zhang J, He F, Chen Y, Zhu J, et al. 2021. Defect and doping co-engineered non-metal nanocarbon ORR electrocatalyst. Nano-Micro Letters 13(1):65

doi: 10.1007/s40820-020-00579-y
[43]

Li M, Liu Z, Wang F, Xuan J. 2017. The influence of the type of N dopping on the performance of bifunctional N-doped ordered mesoporous carbon electrocatalysts in oxygen reduction and evolution reaction. Journal of Energy Chemistry 26:422−427

doi: 10.1016/j.jechem.2017.01.004
[44]

Askari S, Dwivedi S, Alivand MS, Lim KH, Biniaz P, et al. 2025. Synergy of pyridinic-N and Co single atom sites for enhanced oxygen redox reactions in high-performance zinc-air batteries. Small 21(10):2411574

doi: 10.1002/smll.202411574
[45]

Wang XR, Liu JY, Liu ZW, Wang WC, Luo J, et al. 2018. Identifying the key role of pyridinic-N-Co bonding in synergistic electrocatalysis for reversible ORR/OER. Advanced Materials 30(23):1800005

doi: 10.1002/adma.201800005
[46]

Jenkins M, Dewar D, Lagnoni M, Yang S, Rees GJ, et al. 2024. A high capacity gas diffusion electrode for Li–O2 batteries. Advanced Materials 36:2405715

doi: 10.1002/adma.202405715
[47]

Zhang Z, Xiao X, Yan A, Sun K, Yu J, et al. 2023. A quantitative understanding of electron and mass transport coupling in lithium–oxygen batteries. Advanced Energy Materials 13(47):2302816

doi: 10.1002/aenm.202302816
[48]

Chen Y, Xu J, He P, Qiao Y, Guo S, et al. 2022. Metal-air batteries: progress and perspective. Science Bulletin 67:2449−2486

doi: 10.1016/j.scib.2022.11.027
[49]

Liang YL, Yu Y, Li ZW, Yan JM, Huang G, et al. 2024. Mass transfer analysis for achieving high-rate lithium–air batteries. ACS Nano 18:17361−17368

doi: 10.1021/acsnano.4c04529
[50]

Singh SK, Takeyasu K, Nakamura J. 2019. Active sites and mechanism of oxygen reduction reaction electrocatalysis on nitrogen-doped carbon materials. Advanced Materials 31(13):1804297

doi: 10.1002/adma.201804297
[51]

Guo D, Shibuya R, Akiba C, Saji S, Kondo T, et al. 2016. Active sites of nitrogen-doped carbon materials for oxygen reduction reaction clarified using model catalysts. Science 351:361−365

doi: 10.1126/science.aad0832
[52]

Zhao C, Yan Z, Zhou B, Pan Y, Hu A, et al. 2023. Identifying the role of lewis-base sites for the chemistry in lithium-oxygen batteries. Angewandte Chemie International Edition 62(32):e202302746

doi: 10.1002/anie.202302746
[53]

Chen J, Quattrocchi E, Ciucci F, Chen Y. 2023. Charging processes in lithium-oxygen batteries unraveled through the lens of the distribution of relaxation times. Chem 9:2267−2281

doi: 10.1016/j.chempr.2023.04.022
[54]

Johnson L, Li C, Liu Z, Chen Y, Freunberger SA, et al. 2014. The role of LiO2 solubility in O2 reduction in aprotic solvents and its consequences for Li–O2 batteries. Nature Chemistry 6:1091−1099

doi: 10.1038/nchem.2101
[55]

Prehal C, Samojlov A, Nachtnebel M, Lovicar L, Kriechbaum M, et al. 2021. In situ small-angle X-ray scattering reveals solution phase discharge of Li–O2 batteries with weakly solvating electrolytes. Proceedings of the National Academy of Sciences of the United States of America 118:e2021893118

doi: 10.1073/pnas.2021893118
[56]

Karunarathne S, Pérez GE, Wijesinghe WPSL, Orange F, Kannangara YY, et al. 2025. Optimizing discharge product morphology with hetero-nanostructured NiCoP/NiCo2O4 for enhanced sustainability in Li-O2 battery performance. Journal of Materials Chemistry A 13:11344−11357

doi: 10.1039/d4ta08552c
[57]

Li SS, Zhao XL, Liu YS, Liu JJ, Wang KX, et al. 2023. Tailoring the nucleation and growth routes of discharge products for lithium-oxygen batteries through the facet engineering of Ni2P catalysts. Energy Storage Materials 56:506−514

doi: 10.1016/j.ensm.2023.01.023
[58]

Ma L, Meng N, Zhang Y, Lian F. 2019. Improved electrocatalytic activity of δ-MnO2@MWCNTs by inducing the oriented growth of oxygen reduction products in Li-O2 batteries. Nano Energy 58:508−516

doi: 10.1016/j.nanoen.2019.01.089